Australian Museum Journal Composition of pyromorphites from Broken Hill, New South Wales

Shortform:
Inegbenebor et al., 1992, Rec. Aust. Mus., Suppl. 15: 29–37
Author(s):
Inegbenebor, A. I.; Williams, P. A.; Bevins, R. E.; Lambert, M. P.; Hart, Alan D.
Year published:
1992
Title:
Composition of pyromorphites from Broken Hill, New South Wales
Serial title:
Records of the Australian Museum, Supplement
Volume:
15
Start page:
29
End page:
37
DOI:
10.3853/j.0812-7387.15.1992.81
Language:
English
Date published:
16 October 1992
Cover date:
16 October 1992
ISBN:
ISBN 0-7305-9990-6
ISSN:
0812-7387
CODEN:
RAMSEZ
Publisher:
The Australian Museum
Place published:
Sydney, Australia
Subjects:
GEOLOGY; MINERALOGY
Digitized:
28 July 2009
Reference number:
81
EndNote package:
EndNote file
Title page:
Title page (79kb PDF)
Complete work:
Complete work (1410kb PDF)

Abstract

Twenty eight specimens of pyromorphite from the oxidised zone of the Broken Hill orebody, New South Wales have been analysed using EPMA methods. Material was selected to represent all of the varieties of pyromorphite which have been described by earlier workers as occurring in the deposit. Aside from minor Ca2+ substitution for Pb2+ and occasionally VO43- for PO43-, all specimens examined proved to be either pure end-member pyromorphite or arsenian pyromorphite with a maximum arsenate content corresponding to pyr2.1mim0.9. In one specimen phosphate-arsenate zoning is evident; minor vanadate is present in the more arsenian material. Calcium-lead zoning has been detected in a pale grey-coloured specimen. These zoning patterns indicate chemical variations in aqueous solution during crystal growth. The arsenate contents appear to be directly related to the original distribution of the primary arsenides and arsenic-bearing sulfosalts. The compositions have been related to those of the solutions from which they crystallised. Apatite is a major accessory in the primary ore and this would provide the requisite phosphate ions.

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